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• W2527831373 startingPage "1151" @default.
• W2527831373 abstract "Polymeric materials can be directly converted into molecular recognition materials by alternative molecular imprinting. To produce adsorbents that specifically adsorb cesium ions, a polymeric adsorbent was converted from polyacrylonitrile, adopting cesium chloride as a print molecule. The adsorption ability of the molecularly imprinted adsorbent was studied by surface plasmon resonance spectroscopy and atomic absorption analysis. The results revealed that Cs+-recognition sites were formed in the presence of CsCl during the adsorbent preparation process. The affinity constant between Cs+ and and Cs+-recognition sites ranged from 4.2 × 103 to 7.1 × 103 mol−1 dm3. The adsorbents obtained in the present study are expected to be useful for the specific adsorption of Cs+ from nuclear waste. Polymeric materials can be directly converted into molecular recognition materials by applying alternative molecular imprinting. This is expected to produce adsorbents that can specifically adsorb cesium ions. To this end, a polymeric adsorbent was converted from polyacrylonitrile, adopting cesium chloride as a print molecule. As a result, Cs+-recognition sites were formed in the presence of CsCl during the adsorbent preparation process. The adsorbents obtained in the present study are expected to be useful as specific adsorbents for capturing the nuclear waste, Cs+." @default.
• W2527831373 created "2016-10-14" @default.
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• W2527831373 date "2016-10-05" @default.
• W2527831373 modified "2023-09-27" @default.
• W2527831373 title "Molecularly imprinted polyacrylonitrile adsorbents for the capture of Cs+ ions" @default.
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• W2527831373 doi "https://doi.org/10.1038/pj.2016.87" @default.
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