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• W2528161749 endingPage "756" @default.
• W2528161749 startingPage "748" @default.
• W2528161749 abstract "Aimed at the answer the biophysically important question posed in the title of this article, we have first investigated, at the MP2/aug-cc-pVDZ//B3LYP/6-311++G(d,p) level of quantum-mechanical theory, the structural, energetic, and dynamic features of the acquisition of the enzymatically competent conformation by the incorrect А*·А(WC), G·A(WC), A*·G*(WC), and G*·G(WC) DNA base mispairs with the Watson–Crick (WC) geometry – active players on the field of spontaneous point mutagenesis. It is first shown that the characteristic time of these non-dissociative A*·A(WC)↔A*·Asyn(TF), G·A(WC)↔G·Asyn, A*·G*(WC)↔A*·G*syn, and G·G*(WC)↔G·G*syn conformational transitions is much less than the period of time that it is spent by a high-fidelity DNA-polymerase on the incorporation of one nucleotide into the DNA double helix." @default.
• W2528161749 created "2016-10-14" @default.
• W2528161749 creator A5046908935 @default.
• W2528161749 creator A5065463442 @default.
• W2528161749 date "2015-08-01" @default.
• W2528161749 modified "2023-10-15" @default.
• W2528161749 title "How Do Long Improper Purine-Purine Pairs of DNA Bases Adapt The Enzymatycally Competent Conformation? Structural Mechanism And Its Quantum-Mechanical Grounds" @default.
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• W2528161749 doi "https://doi.org/10.15407/ujpe60.08.0748" @default.
• W2528161749 hasPublicationYear "2015" @default.
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