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• W2528261903 endingPage "811" @default.
• W2528261903 startingPage "808" @default.
• W2528261903 abstract "After electrochemically extracting lithium ions from LiNi0.5Mn1.5O4, we have investigated the structural variation during the relaxation process by means of X-ray diffraction coupled with the Rietveld analysis, assuming Li-rich and Li-lean spinel phases with symmetry coexistence. For both x = 0.1 and 0.2 of LixNi0.5Mn1.5O4, mole fraction of Li-lean phase decreases with the relaxation time, although any apparent change in lattice parameter does not occur for both phases. This indicates that Li-lean phase with larger oxygen tetrahedron size, presumably favorable for lithium diffusion, is formed with excess amount during the lithium extraction, and then it transforms into Li-rich and Li-lean phases with smaller lithium concentration during the relaxation process. Slight increase in the size of oxygen tetrahedron and decrease in that of octahedron during relaxation for Li-lean phase of x = 0.1 are also consistent with above phase change." @default.
• W2528261903 created "2016-10-14" @default.
• W2528261903 creator A5023875457 @default.
• W2528261903 creator A5033110052 @default.
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• W2528261903 date "2016-01-01" @default.
• W2528261903 modified "2023-10-02" @default.
• W2528261903 title "Relaxation Analysis of LiNi_0.5Mn_1.5O₄ 5 V Cathode Material by Means of the Rietveld Refinement" @default.
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• W2528261903 doi "https://doi.org/10.5796/electrochemistry.84.808" @default.
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