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- W2528356912 abstract "Quinolizidine alkaloids epi-cermizine C and epimyrtine were synthesized from a common intermediate in 5–6 steps from commercially available materials. The key step involved an allylsilane cyclization with an iminium ion formed by oxidation of a tertiary amine. Oxidative annulation was promoted either catalytically by visible light photoredox catalysis or by stoichiometric Polonovski-Potier conditions. There was a modest difference in diastereoselectivity between the two methods, with photoredox providing the key quinolizidine intermediate in 4.7:1 dr versus 2:1 dr for the Polonovski route." @default.
- W2528356912 created "2016-10-14" @default.
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- W2528356912 date "2016-11-01" @default.
- W2528356912 modified "2023-10-16" @default.
- W2528356912 title "Visible light photoredox and Polonovski-Potier cyclizations for the synthesis of (±)-5-epi-cermizine C and (±)-epimyrtine" @default.
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- W2528356912 doi "https://doi.org/10.1016/j.tetlet.2016.10.007" @default.
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