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- W2528392203 abstract "Novel electropolymerized films that naturally appeared gold-like and possessed lustrous green color tones were prepared by the cyclic potential-sweep electropolymerization of 3-methoxythiophene. The polymerized products were characterized by different instrumentation techniques, which identified them as oligo(3-methoxythiophene) containing perchlorate and dodecyl sulfate anions. The optical and structural analyses demonstrated that the films consisted of edge-on and face-on lamellar structures of the oligomers, and that the edge-on structures contributed to the development of the gold-like luster. The role of the cyclic potential sweep was interpreted as the preferential destruction of the face-on lamellar structures and a contribution to the increasing effects of the edge-on lamellar structures. The first oligo(3-methoxythiophene) films that naturally appeared gold-like and lustrous green color tones were prepared by the cyclic potential-sweep electropolymerization of 3-methoxythiophene. Control experiments and optical/structural analyses showed that the films consisted of the edge-on and face-on lamella structures of the oligomers, and that the former structure contributed to the development of gold-like luster. Also, it was suggested that the action of the cyclic potential sweep was to preferentially destroy the face-on lamella, highlight the effect of the edge-on lamella, and develop gold-like luster." @default.
- W2528392203 created "2016-10-14" @default.
- W2528392203 creator A5059485468 @default.
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- W2528392203 date "2016-10-05" @default.
- W2528392203 modified "2023-10-18" @default.
- W2528392203 title "Electropolymerized films of 3-methoxythiophene with a potential sweep-induced gold-like luster" @default.
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- W2528392203 doi "https://doi.org/10.1038/pj.2016.86" @default.
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