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- W2528931447 abstract "Cascade radical cyclization of alkynyl ketones with various carbon- and heteroatom-centered radical precursors via a sequential radical addition/1,5-H radical shift/5-exo-trig/radical cyclization process was realized for the first time. This method provides a strategically novel and step-economical protocol for diversity-oriented synthesis of a wide range of carbocyclic and heterocyclic 6(5)-6-5 fused ring systems with three contiguous stereocenters, including a quaternary carbon in high yields with excellent chemo- and diastereoselectivity." @default.
- W2528931447 created "2016-10-14" @default.
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- W2528931447 date "2016-10-04" @default.
- W2528931447 modified "2023-10-16" @default.
- W2528931447 title "Stereoselective Radical Cyclization Cascades Triggered by Addition of Diverse Radicals to Alkynes To Construct 6(5)–6–5 Fused Rings" @default.
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- W2528931447 doi "https://doi.org/10.1021/acs.orglett.6b02599" @default.
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