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- W2529737548 abstract "Abstract We systematically investigated the structural properties of as-deposited and annealed Ge x Sb y Se z ( x + y + z = 100, 9.5 ≤ x ≤ 59, 6.2 ≤ y ≤ 42.9, 34.8 ≤ z ≤ 51.5) chalcogenide films. For films with x Sb homopolar bonds as well as Sb Se heteropolar bonds appeared in the as-deposited films, while increasing the Ge content replaced some Se atoms, forming Ge Se heteropolar bonds, which increased the optical band gap. For films with x ≥ 34.5, the structures of the as-deposited films were dominated by Ge Ge and Se Se homopolar bonds. The annealed Ge–Sb–Se films exhibited a phase transition from amorphous to crystalline for phase-change memory. We ascribed the crystal grains of the Ge x Sb y Se z films ( x = 9.5, 12.8) to be the Sb phase, while we confirmed those of the films ( x = 14.2, 21.3, 22.9, 25.2) to be a mixture of Sb and Sb 2 Se 3 phases. The films with high Ge content ( x = 40.2, 59) exhibited a stable amorphous phase for optical waveguide application." @default.
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- W2529737548 date "2016-12-01" @default.
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- W2529737548 title "Compositional dependence of crystallization and structural stability in Ge–Sb–Se chalcogenide films" @default.
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- W2529737548 doi "https://doi.org/10.1016/j.jnoncrysol.2016.10.003" @default.
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