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• W2529972705 abstract "The synthesis of vitamin B12 in four steps from an artificial green secocorrinoid is presented. The stereospecific reconstitution of the B-ring of the cobalamin involves a quantitative and rapid ligand-centered radical ring closure reaction leading first to a new B12 derivative with antivitamin activity that is subsequently converted to the natural product. Chemoselectivity in the one-electron reduction of the macrocycle was achieved by introducing inorganic cyanide as an axially coordinating protecting group of the otherwise reduction-sensitive CoIII-ion. The integrity of structure and function of the reconstituted natural product was unequivocally proven by single crystal structural analysis and a microbiological assay using Lactobacillus leichmannii." @default.
• W2529972705 created "2016-10-21" @default.
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• W2529972705 date "2016-10-11" @default.
• W2529972705 modified "2023-09-27" @default.
• W2529972705 title "Inorganic Cyanide as Protecting Group in the Stereospecific Reconstitution of Vitamin B₁₂ from an Artificial Green Secocorrinoid" @default.
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• W2529972705 doi "https://doi.org/10.1021/acs.orglett.6b02611" @default.
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