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- W2530496354 abstract "A hexapyrrolohexaazacoronene derivative containing 37 fused rings, the largest such system to date, was obtained from a naphthalenomonoimide-pyrrole hybrid in a concise and efficient synthesis. This large heterocycle is electron-deficient and shows extended redox activity, spanning at least 13 oxidation levels, but is otherwise chemically stable. Radial expansion of the π system creates a chromophore characterized by strong fluorescence and solvatochromism in the neutral state, and strong near-infrared absorption in the charged states. Additionally, the enlarged and ruffled aromatic surface supports a unique self-assembly mode in the crystal, leading to the formation of highly solvated organic clathrates." @default.
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- W2530496354 date "2016-10-14" @default.
- W2530496354 modified "2023-10-14" @default.
- W2530496354 title "An Electron‐Deficient Azacoronene Obtained by Radial π Extension" @default.
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- W2530496354 doi "https://doi.org/10.1002/anie.201608400" @default.
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