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- W2530657190 abstract "[Fe4S4(SCH 2 CH 2 COO-)4] 6- , which acts as active center analogue of ferredoxin, demonstrates a proton coupled electron transfer phenomenon with pK a 0x at 3.0, 2.5, and 3.2 and pK a Red at 4.7, 4.3, and 4.8, in 3% (w/v) aqueous SDS, TX-100 and CTAB micelles. When the operating pH is between pK a Ox and pK a Red , the observed redox Bohr effect exhibits a 60 to 70 mV per pH unit slope indicating one proton per electron coupled event. These low pK a values arise because of the protonation/deprotonation of one of the four carboxylates. Also, protonation of the carboxylate leads to 120-140 mV positive shift in the mid-point potential. Formation of H bonding between the carboxylate and the neighbouring protonated core S is proposed as reason for the very low pKa." @default.
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- W2530657190 date "2005-08-01" @default.
- W2530657190 modified "2023-09-26" @default.
- W2530657190 title "Redox linked protonation/deprotonation on the carboxylate of [Fe 4 S 4 (SCH 2 CH 2 COO - ) 4 ] 6- in aqueous micellar solutions" @default.
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