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• W2530965504 abstract "Herein we describe the first approach to 3-oxidopyrylium ions from a linear precursor. Heating bis(1-cyanovinyl acetate) in the presence of a trace amount of pyridinium p-toluenesulfonate results in a series of acyl group transfers and an intramolecular cyclization event to form a 3-oxidopyrylium ion that can be trapped by reaction with several dipolarophiles. When treated with dienes, the result is a sequential [5 + 2]/[4 + 2] cycloaddition reaction that provides sp3-rich products of high molecular complexity." @default.
• W2530965504 created "2016-10-21" @default.
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• W2530965504 date "2016-11-01" @default.
• W2530965504 modified "2023-09-24" @default.
• W2530965504 title "Bis(1-cyanovinyl acetate) Is a Linear Precursor to 3-Oxidopyrylium Ions" @default.
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• W2530965504 doi "https://doi.org/10.1021/acs.joc.6b02111" @default.
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