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• W2531037580 abstract "An enantio- and diastereoselective synthesis of the C17–C29 fragment of amphidinolide N, an extremely potent macrocyclic cytotoxin of marine origin, has been accomplished from a known olefinic ester by a 10-step sequence that involves a ring opening of a chiral epoxide with a dithiane derivative to construct the full carbon skeleton, a highly diastereoselective reduction of a β-hydroxy ketone intermediate to install the C21 asymmetric center, and a one-pot Sharpless AD/cyclization sequence to form a trans-substituted tetrahydrofuran ring system." @default.
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• W2531037580 date "2016-11-01" @default.
• W2531037580 modified "2023-10-10" @default.
• W2531037580 title "Stereoselective synthesis of the C17–C29 fragment of amphidinolide N" @default.
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• W2531037580 doi "https://doi.org/10.1016/j.tetlet.2016.10.038" @default.
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