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- W2531194719 abstract "One known and nine new quaternary aluminides in the Al-rich region of R – T –Ag–Al ( R = Y, Ce, Pr, Nd, Sm, and Gd, T = V, Nb, Ta, Cr, and Mo) systems were synthesized by arc melting and their crystal structures were studied by X-ray powder diffraction. The crystal structures of the compounds R 3 T (Ag,Al) 20 Al 12 ( R = Ce, Pr, Nd, and Sm, T = V, Nb, Ta, Cr, and Mo) and R 3 T Ag x (Ag,Al) 20 Al 12 ( R = Y and Gd, T = Ta) belong to new structure types: Ce 3 Ta (Ag,Al) 20 Al 12 (Pearson symbol сP 36, space group Pm -3 m , a = 8.6675(2) Å) and Gd 3 TaAg x (Ag,Al) 20 Al 12 ( сP 4912.86, Pm -3 m , a = 8.6158(5) Å), respectively. Within the rows of isotypic compounds the unit-cell parameter increases with increasing metallic radius of the rare-earth or d -element atom. The structure type Ce 3 Ta (Ag,Al) 20 Al 12 (Ce 3 TaAg 7.97 Al 24.03 ) is a partly ordered quaternary substitution derivative of the structure type BaHg 11 , whereas Gd 3 TaAg x (Ag,Al) 20 Al 12 (Gd 3 TaAg 8.89 Al 23.25 ) is a distorted fill-in quaternary substitution variant of the same prototype. The latter can also be described as a derivative of the structure type Y 3 TaNi 6+x Al 26 ." @default.
- W2531194719 created "2016-10-21" @default.
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- W2531194719 date "2016-10-01" @default.
- W2531194719 modified "2023-09-24" @default.
- W2531194719 title "Quaternary Derivatives of the Structure Type BaHg<sub>11</sub>" @default.
- W2531194719 doi "https://doi.org/10.4028/www.scientific.net/ssp.257.64" @default.
- W2531194719 hasPublicationYear "2016" @default.
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