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- W2531203529 abstract "The thermal stability and kinetics of isothermal decomposition of diosgenin were studied by ther� mogravimetry (TG) and Differential Scanning Calorimeter (DSC). The activation energy of the thermal decomposition process was determined from the analysis of TG curves by the methods of Flynn-Wall- Ozawa, Doyle, Satava�Sestak and Kissinger, respectively. The mechanism of thermal decomposition was determined to be Avrami-Erofeev equation (n = 1/3, n is the reaction order) with integral form G(α) = ( ⎯ln(1 - α)) 1/3 (α = 0.10-0.80). Ea and logA (s -1 ) were determined to be 44.10 kJ mol -1 and 3.12, respec� tively. Moreover, the thermodynamics properties of ΔH ≠ , ΔS ≠ , and ΔG ≠ of this reaction were 38.18 kJ mol -1 , -199.76 J mol -1 K -1 , and 164.36 kJ mol -1 in the stage of thermal decomposition." @default.
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- W2531203529 date "2013-01-01" @default.
- W2531203529 modified "2023-09-27" @default.
- W2531203529 title "CHEMICAL KINETICS AND CATALYSIS NonIsothermal Decomposition Kinetics of Diosgenin 1" @default.
- W2531203529 hasPublicationYear "2013" @default.
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