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- W253146670 abstract "Summary Infrared absorption and Raman scattering spectra were recorded after the cation exchange (K+, Cs+) of the as-synthesized silica-rich hexagonal (EMT) polytype of the faujasite zeolite. The spectra provide evidence for the conformation and the complexation of the occluded crown ether 18C6 used as template. Particularly, two types of 18C6 molecules have been detected in the dehydrated samples, corresponding probably to the two types of large cages where the molecules are occluded. The in situ vibrational spectra recorded during the thermal treatment of the as-synthesized material and the cracking pattern of 18C6 are in good agreement with ethylenic intermediates. Others applications of infrared and Raman spectroscopies in the mid and low-frequency regions to dynamics of bare EMT framework and extraframework cations of exchanged samples were evaluated as well and compared with the corresponding results concerning the silica-rich cubic faujasite, FAU, obtained using 15C5 as template." @default.
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- W253146670 date "1994-01-01" @default.
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- W253146670 title "Vibrational spectroscopic investigations of the cation exchange and thermal activation of the silica-rich hexagonal polytype of faujasitic zeolites" @default.
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- W253146670 doi "https://doi.org/10.1016/s0167-2991(08)63638-1" @default.
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