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- W2531477900 abstract "All-solid-state Li-ion batteries having incombustible solid electrolytes are promising energy storage devices because they have significant advantages in terms of safety, lifetime and energy density. Electrochemical reactions, namely, Li-ion insertion/extraction reactions, commonly occur around the nanometer-scale interfaces between the electrodes and solid electrolytes. Thus, transmission electron microscopy (TEM) is an appropriate technique to directly observe such reactions, providing important information for understanding the fundamental solid-state electrochemistry and improving battery performance. In this review, we introduce two types of TEM techniques for operando observations of battery reactions, spatially resolved electron energy-loss spectroscopy in a TEM mode for direct detection of the Li concentration profiles and electron holography for observing the electric potential changes due to Li-ion insertion/extraction reactions. We visually show how Li-ion insertion/extractions affect the crystal structures, electronic structures, and local electric potential during the charge-discharge processes in these batteries." @default.
- W2531477900 created "2016-10-21" @default.
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- W2531477900 date "2016-12-06" @default.
- W2531477900 modified "2023-09-27" @default.
- W2531477900 title "Operando observations of solid-state electrochemical reactions in Li-ion batteries by spatially resolved TEM EELS and electron holography" @default.
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- W2531477900 doi "https://doi.org/10.1093/jmicro/dfw106" @default.
- W2531477900 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27927876" @default.
- W2531477900 hasPublicationYear "2016" @default.
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