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- W2531640219 abstract "various trigonal borons present and provided an opportunity to test speciation models in the highalkali region. Surprisingly, these experiments also found significant differences between the network structure of lithium borates and those of the other alkali borate glasses, where lower-field NMR studies found none. Furthermore, the cation disorder and paramagnetic impurities often present in natural minerals can cause peak broadening which compromises site resolution and quantification in borosilicates. Using the ultrahigh-field NMR facility, well-resolved 11 B MAS NMR spectra could be obtained for tourmalines, allowing straightforward analysis of the total and fractional boron contents, quantities not easily accessible by conventional techniques such as x-ray diffraction and electronmicroprobe analysis. Reduced quadrupolar broadening and amplified chemical shift dispersion at high field combine to produce excellent site resolution and quantification required to determine key aspects of short- and medium-range ordering in borates." @default.
- W2531640219 created "2016-10-21" @default.
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- W2531640219 date "2007-01-01" @default.
- W2531640219 modified "2023-09-27" @default.
- W2531640219 title "Characterization of borate glasses, crystals and minerals" @default.
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