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• W2531706588 abstract "It is of interest to develop two-component systems for added flexibility in the design of supramolecular polymers, nanofibers, or organogels. Bisureas are known to self-assemble by hydrogen bonding into long supramolecular objects. We show here that mixing aromatic bisureas with slightly different structures can yield surprisingly large synergistic effects. A strong increase in viscosity is observed when a bisurea with the sterically demanding 2,4,6-trimethylbenzene spacer is combined with a bisurea bearing no methyl group in position 2 of the aromatic spacer (i.e., 4-methylbenzene or 4,6-dimethylbenzene). This effect is the consequence of a change in the supramolecular assembly triggered by the composition of the mixture. The mixture of complementary bisureas forms rodlike objects that are more stable by about 1 kJ/mol and that are thicker than the rodlike objects formed by both parent systems." @default.
• W2531706588 created "2016-10-21" @default.
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• W2531706588 date "2016-10-19" @default.
• W2531706588 modified "2023-09-25" @default.
• W2531706588 title "Two-Component Self-Assemblies: Investigation of a Synergy between Bisurea Stickers" @default.
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• W2531706588 doi "https://doi.org/10.1021/acs.langmuir.6b03325" @default.
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