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- W2531775997 abstract "Abstract A linear viologen (bis[4-(4-pyridinyl)phenyl] viologen, BPPV) characterized by a fully-conjugated structure was synthesized through Zinke reaction. BPPV consists of a unique linear sexiaryl structure and is apt to be encapsulated by cucurbit[n]uril (CB[n], n = 6 or 7) in aqueous solution, forming a [2]pseudorotaxane (BPPV ⊂ CB[6]) with CB[6] in a central-included mode and a final [3]pseudorotaxane (BPPV ⊂ 2CB[7]) with CB[7] in a side-included manner. The reduction potentials became higher for BPPV ⊂ 2CB[7], and the highest for BPPV ⊂ CB[6] when compared with BPPV. BPPV, BPPV ⊂ CB[6] and BPPV ⊂ 2CB[7] all underwent reversible one-electron redox reaction in aqueous solution, accompanied by obvious color changes, showing a good prospect in the fabrication of electrochromic display devices." @default.
- W2531775997 created "2016-10-21" @default.
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- W2531775997 date "2017-02-01" @default.
- W2531775997 modified "2023-09-23" @default.
- W2531775997 title "The synthesis of a rigid conjugated viologen and its cucurbituril pseudorotaxanes" @default.
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- W2531775997 doi "https://doi.org/10.1016/j.dyepig.2016.10.012" @default.
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