FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2531827375> ?p ?o ?g. }

• W2531827375 endingPage "30629" @default.
• W2531827375 startingPage "30622" @default.
• W2531827375 abstract "The 3-dimensional (3D) atomic-scale structure of newly discovered face-centered cubic (fcc) and conventional hexagonal close packed (hcp) type ruthenium (Ru) nanoparticles (NPs) of 2.2 to 5.4 nm diameter were studied using X-ray pair distribution function (PDF) analysis and reverse Monte Carlo (RMC) modeling. Atomic PDF based high-energy X-ray diffraction measurements show highly diffuse X-ray diffraction patterns for fcc- and hcp-type Ru NPs. We here report the atomic-scale structure of Ru NPs in terms of the total structure factor and Fourier-transformed PDF. It is found that the respective NPs have substantial structural disorder over short- to medium-range order atomic distances from the PDF analysis. The first-nearest-neighbor peak analyses show a significant size dependence for the fcc-type Ru NPs demonstrating the increase in the peak height due to an increase in the number density as a function of particle size. The bond angle and coordination number (CN) distribution for the RMC-simulated fcc- and hcp-type Ru NP models indicated inherited structural features from their bulk counterparts. The CN analysis of the whole NP and surface of each RMC model of Ru NPs show the low activation energy packing sites on the fcc-type Ru NP surface atoms. Finally, our newly defined order parameters for RMC simulated Ru NP models suggested that the enhancement of the CO oxidation activity of fcc-type NPs was due to a decrease in the close packing ordering that resulted from the increased NP size. These structural findings could be positively supported for synthesized low-cost and high performance nano-sized catalysts and have potential application in fuel-cell systems and organic synthesis." @default.
• W2531827375 created "2016-10-21" @default.
• W2531827375 creator A5012966085 @default.
• W2531827375 creator A5026256304 @default.
• W2531827375 creator A5057253611 @default.
• W2531827375 creator A5058070302 @default.
• W2531827375 creator A5078871000 @default.
• W2531827375 creator A5082806629 @default.
• W2531827375 creator A5083161182 @default.
• W2531827375 creator A5091600306 @default.
• W2531827375 date "2016-01-01" @default.
• W2531827375 modified "2023-10-10" @default.
• W2531827375 title "Origin of the catalytic activity of face-centered-cubic ruthenium nanoparticles determined from an atomic-scale structure" @default.
• W2531827375 cites W1970096755 @default.
• W2531827375 cites W1977456452 @default.
• W2531827375 cites W1984803338 @default.
• W2531827375 cites W1990854698 @default.
• W2531827375 cites W2009518777 @default.
• W2531827375 cites W2014300566 @default.
• W2531827375 cites W2032567999 @default.
• W2531827375 cites W2046991096 @default.
• W2531827375 cites W2080548006 @default.
• W2531827375 cites W2083560442 @default.
• W2531827375 cites W2084857400 @default.
• W2531827375 cites W2087801484 @default.
• W2531827375 cites W2100795821 @default.
• W2531827375 cites W2102362645 @default.
• W2531827375 cites W2109046363 @default.
• W2531827375 cites W2125042418 @default.
• W2531827375 cites W2129114560 @default.
• W2531827375 cites W2137301424 @default.
• W2531827375 cites W2142825246 @default.
• W2531827375 cites W2154746844 @default.
• W2531827375 cites W2167434176 @default.
• W2531827375 cites W2478797869 @default.
• W2531827375 cites W2546839804 @default.
• W2531827375 cites W3104905848 @default.
• W2531827375 cites W4236347495 @default.
• W2531827375 cites W4301418733 @default.
• W2531827375 doi "https://doi.org/10.1039/c6cp04088h" @default.
• W2531827375 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27787531" @default.
• W2531827375 hasPublicationYear "2016" @default.
• W2531827375 type Work @default.
• W2531827375 sameAs 2531827375 @default.
• W2531827375 citedByCount "37" @default.
• W2531827375 countsByYear W25318273752017 @default.
• W2531827375 countsByYear W25318273752018 @default.
• W2531827375 countsByYear W25318273752019 @default.
• W2531827375 countsByYear W25318273752020 @default.
• W2531827375 countsByYear W25318273752021 @default.
• W2531827375 countsByYear W25318273752022 @default.
• W2531827375 countsByYear W25318273752023 @default.
• W2531827375 crossrefType "journal-article" @default.
• W2531827375 hasAuthorship W2531827375A5012966085 @default.
• W2531827375 hasAuthorship W2531827375A5026256304 @default.
• W2531827375 hasAuthorship W2531827375A5057253611 @default.
• W2531827375 hasAuthorship W2531827375A5058070302 @default.
• W2531827375 hasAuthorship W2531827375A5078871000 @default.
• W2531827375 hasAuthorship W2531827375A5082806629 @default.
• W2531827375 hasAuthorship W2531827375A5083161182 @default.
• W2531827375 hasAuthorship W2531827375A5091600306 @default.
• W2531827375 hasBestOaLocation W25318273751 @default.
• W2531827375 hasConcept C121332964 @default.
• W2531827375 hasConcept C127413603 @default.
• W2531827375 hasConcept C144024400 @default.
• W2531827375 hasConcept C155672457 @default.
• W2531827375 hasConcept C159467904 @default.
• W2531827375 hasConcept C161790260 @default.
• W2531827375 hasConcept C171250308 @default.
• W2531827375 hasConcept C178790620 @default.
• W2531827375 hasConcept C185592680 @default.
• W2531827375 hasConcept C192562407 @default.
• W2531827375 hasConcept C24444364 @default.
• W2531827375 hasConcept C2778755073 @default.
• W2531827375 hasConcept C2779304628 @default.
• W2531827375 hasConcept C36289849 @default.
• W2531827375 hasConcept C42360764 @default.
• W2531827375 hasConcept C555196967 @default.
• W2531827375 hasConcept C62520636 @default.
• W2531827375 hasConcept C66823137 @default.
• W2531827375 hasConcept C8010536 @default.
• W2531827375 hasConceptScore W2531827375C121332964 @default.
• W2531827375 hasConceptScore W2531827375C127413603 @default.
• W2531827375 hasConceptScore W2531827375C144024400 @default.
• W2531827375 hasConceptScore W2531827375C155672457 @default.
• W2531827375 hasConceptScore W2531827375C159467904 @default.
• W2531827375 hasConceptScore W2531827375C161790260 @default.
• W2531827375 hasConceptScore W2531827375C171250308 @default.
• W2531827375 hasConceptScore W2531827375C178790620 @default.
• W2531827375 hasConceptScore W2531827375C185592680 @default.
• W2531827375 hasConceptScore W2531827375C192562407 @default.
• W2531827375 hasConceptScore W2531827375C24444364 @default.
• W2531827375 hasConceptScore W2531827375C2778755073 @default.
• W2531827375 hasConceptScore W2531827375C2779304628 @default.
• W2531827375 hasConceptScore W2531827375C36289849 @default.
• W2531827375 hasConceptScore W2531827375C42360764 @default.
• W2531827375 hasConceptScore W2531827375C555196967 @default.
• W2531827375 hasConceptScore W2531827375C62520636 @default.

• next