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- W2531992373 abstract "A neutron diffraction measurements and molecular dynamics simulations have been performed to study the hydrogen bonded structure of water-formamide mixtures. We showed that the calculated and measured total neutron diffraction radial distribution function agreed very well. After evaluation of this function, the hydrogen-bonded structure of mixtures with various compositions has been studied, and the clustering properties and the topology of the hydrogen-bonded network were investigated. The results show that these mixtures exhibit an extended range structure in solution. In water-formamide mixtures the average number of hydrogen bonded neighbors (water, formamide) and the distribution of the number of H-bonded neighbors do not change significantly as a function of the formamide mole fraction. Molecules are shown to form percolated networks at each concentration. The composition of cyclic entities in these systems is very close to being ideal; that is, these systems are microscopically homogeneous." @default.
- W2531992373 created "2016-10-28" @default.
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- W2531992373 date "2017-02-01" @default.
- W2531992373 modified "2023-10-18" @default.
- W2531992373 title "Water-formamide mixtures: Topology of the hydrogen-bonded network" @default.
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- W2531992373 doi "https://doi.org/10.1016/j.molliq.2016.10.052" @default.
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