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• W2532661569 endingPage "1602507" @default.
• W2532661569 startingPage "1602507" @default.
• W2532661569 abstract "Rational design of cost-effective, nonprecious metal-based catalysts with desirable oxygen reduction reaction (ORR) performance is extremely important for future fuel cell commercialization, etc. Herein, a new type of ORR catalyst of Co-N-doped mesoporous carbon hollow sphere (Co-N-mC) was developed by pyrolysis from elaborately fabricated polystyrene@polydopamine-Co precursors. The obtained catalysts with active Co sites distributed in highly graphitized mesoporous N-doped carbon hollow spheres exhibited outstanding ORR activity with an onset potential of 0.940 V, a half-wave potential of 0.851 V, and a small Tafel slope of 45 mV decade-1 in 0.1 m KOH solution, which was comparable to that of the Pt/C catalyst (20%, Alfa). More importantly, they showed superior durability with little current decline (less than 4%) in the chronoamperometric evaluation over 60 000 s. These features make the Co-N-mC one of the best nonprecious-metal catalysts to date for ORR in alkaline condition." @default.
• W2532661569 created "2016-10-28" @default.
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• W2532661569 date "2016-10-18" @default.
• W2532661569 modified "2023-10-12" @default.
• W2532661569 title "Co-N-Doped Mesoporous Carbon Hollow Spheres as Highly Efficient Electrocatalysts for Oxygen Reduction Reaction" @default.
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• W2532661569 doi "https://doi.org/10.1002/smll.201602507" @default.
• W2532661569 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27753222" @default.
• W2532661569 hasPublicationYear "2016" @default.
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