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• W2533084581 endingPage "14871" @default.
• W2533084581 startingPage "14867" @default.
• W2533084581 abstract "The thermal gas-phase reactions of the closed-shell metal-oxide cluster [Al2 TaO5 ]+ with methane have been explored by using FT-ICR mass spectrometry complemented by high-level quantum chemical calculations. Mechanistic aspects have been addressed to reveal the origins of the efficient addition process which results in activating the C-H bond of methane. The [Al2 TaO5 ]+ /CH4 couple has been compared with several other systems reported previously, and the electronic origins of their rather distinct performances are discussed." @default.
• W2533084581 created "2016-10-28" @default.
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• W2533084581 date "2016-10-24" @default.
• W2533084581 modified "2023-09-30" @default.
• W2533084581 title "The Origin of the Efficient, Thermal Chemisorption of Methane by the Heteronuclear Metal‐Oxide Cluster [Al ₂ TaO ₅ ] ⁺" @default.
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• W2533084581 doi "https://doi.org/10.1002/anie.201608999" @default.
• W2533084581 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27775207" @default.
• W2533084581 hasPublicationYear "2016" @default.
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