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- W2534414865 abstract "Often the paramagnetic defects have important impact on the nuclear relaxation even in the “nominally” pure samples. These effects show themselves either by the nearest-neighbors only or by the dipolar long-range interaction. The former are addressed in this paper in which we built a model for calculation of T1, T1Q, T2, T1ρ when there is—or not—a residual quadrupolar interaction. This model shows that the maxima of R2 = 1/T2 and R1ρ = 1/T1ρ are shifted toward the low frequencies (low temperatures with regards to the one of R1 = 1/T1), the maximum of R1ρ is shifted toward the low frequencies with regards to the one of R2, and this model is general and can be applied to any system which relaxes by transferred hyperfine interaction. This model was applied to Li1.3Al0.3Ti1.7(PO4)3. It accounts for all the experimental results of T1 (6Li), T1 (7Li), T1Q (7Li), T2 (7Li), and T1ρ (7Li) which were used to highlight local dynamic properties of the lithium versus temperature. The analysis of these results allows u..." @default.
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- W2534414865 date "2016-11-11" @default.
- W2534414865 modified "2023-10-06" @default.
- W2534414865 title "NMR Investigations in Li1.3Al0.3Ti1.7(PO4)3 Ceramics Part II: Lithium Dynamics, Experiments, and Model" @default.
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- W2534414865 doi "https://doi.org/10.1021/acs.jpcc.6b10392" @default.
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