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- W2534806415 abstract "The dichromium(III)-containing heteropoly-16-tungstates [CrIII2(B-β-SiIVW8O31)2]14- (1) and [CrIII2(B-β-GeIVW8O31)2]14- (2) were prepared via a one-pot reaction of the composing elements in aqueous, basic medium. Polyanions 1 and 2 represent the first examples of CrIII-containing heteropolytungstates comprising the octatungstate unit {XW8O31} (X = Si, Ge). Magnetic studies demonstrated that, in the solid state, the two polyanions exhibit a weak antiferromagnetic interaction between the two CrIII centers with J = -3.5 ± 0.5 cm-1, with no long-range ordering down to 1.8 K. The ground-state spin of polyanions 1 and 2 was thus deduced to be 0, but the detection of a complex set of EPR signals implies that there are thermally accessible excited states containing unpaired spins resulting from the two S = 3/2 CrIII ions. A comprehensive electrochemistry study on 1 and 2 in solution was performed, and biological tests showed that both polyanions display significant antidiabetic and anticancer activities." @default.
- W2534806415 created "2016-10-28" @default.
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- W2534806415 date "2016-10-21" @default.
- W2534806415 modified "2023-10-01" @default.
- W2534806415 title "CrIII-Substituted Heteropoly-16-Tungstates [CrIII2(B-β-XIVW8O31)2]14– (X = Si, Ge): Magnetic, Biological, and Electrochemical Studies" @default.
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- W2534806415 doi "https://doi.org/10.1021/acs.inorgchem.6b01458" @default.
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