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• W2535628952 abstract "Catalytic oxymethane reforming is an effective and efficient route to produce syngas, but the commonly used Ni catalysts suffer from coke deposition, Ni sintering, and heat-transfer limitations. A Ni-foam-structured NiO-MgO-Al2O3 nanocomposite catalyst was developed by thermal decomposition of NiMgAl layered double hydroxides (LDHs) in situ hydrothermally grown onto the Ni-foam. Originating from the lattice orientation effect and topotactic decomposition of the LDH precursor, NiO, MgO, and Al2O3 are highly distributed in the nanocomposite, and thus, this catalyst shows enhanced resistance to coke and sintering. At 700 °C and a gas hourly space velocity of 100 L g−1 h−1, 86.5 % methane conversion and selectivities of 91.8/88.0 % to H2/CO are achieved with stability for at least 200 h. We believe this type of tailoring strategy and the as-obtained materials can open up new opportunities for future applications in other high-throughput and high-temperature reactions." @default.
• W2535628952 created "2016-10-28" @default.
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• W2535628952 date "2016-12-14" @default.
• W2535628952 modified "2023-10-16" @default.
• W2535628952 title "Foam-Structured NiO-MgO-Al₂O₃Nanocomposites Derived from NiMgAl Layered Double Hydroxides In Situ Grown onto Nickel Foam: A Promising Catalyst for High-Throughput Catalytic Oxymethane Reforming" @default.
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• W2535628952 doi "https://doi.org/10.1002/cctc.201601167" @default.
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