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- W2536012118 abstract "Abstract A novel dithiocarbazate derivative ligand based on triphenylamine with D-π-A model (HL) and its corresponding transition metal complexes were designed, synthesized and fully characterized. The crystal structures of NiL2 and CuL2 have been confirmed by single crystal X-ray diffraction analysis, indicating that the coordinates to metal-ion to form a five-membered chelated ring with an excellent square-planar conformation, which further form high electron delocalization. Crystal structure determination also confirmed that the structures of NiL2 and CuL2 are isostructural. Open and closed aperture Z-scan measurements were devoted to explore the third-order nonlinear optical (NLO) properties with the aid of femtosecond pulse laser from 680 to 1080 nm. The results revealed that complexes NiL2 and CuL2 possessed large 2PA cross-sections 11235.33 and 12018.99 GM, as well as optical power limiting properties." @default.
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- W2536012118 date "2017-01-01" @default.
- W2536012118 modified "2023-10-18" @default.
- W2536012118 title "Syntheses, characterizations and third-order NLO properties of a series of Ni(II), Cu(II) and Zn(II) complexes using a novel S-benzyldithiocarbazate ligand" @default.
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- W2536012118 doi "https://doi.org/10.1016/j.poly.2016.09.025" @default.
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