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• W2536350097 endingPage "17297" @default.
• W2536350097 startingPage "17291" @default.
• W2536350097 abstract "Treatment of [M2 (μ-Cl)2 (cod)2 ] (M=Ir and Rh) with Na[H2 B(bt)2 ] (cod=1,5-cyclooctadiene and bt=2-mercaptobenzothiazolyl) at low temperature led to the formation of dimetallaheterocycles [(Mcod)2 (bt)2 ], 1 and 2 (1: M=Ir and 2: M=Rh) and a borate complex [Rh(cod){κ2 -S,S'-H2 B(bt)2 }], 3. Compounds 1 and 2 are structurally characterized metal analogues of 1,5-cyclooctadiene. Metal-metal bond distances of 3.6195(9) Å in 1 and 3.6749(9) Å in 2 are too long to consider as bonding. In an attempt to generate the Ru analogue of 1 and 2, that is [(Rucod)2 (bt)2 ], we have carried out the reaction of [Ru(Cl)2 (cod)(CH3 CN)2 ] with Na[H2 B(bt)2 ]. Interestingly, the reaction yielded agostic complexes [Ru(cod)L{κ3 -H,S,S'-H2 B(bt)2 }], 4 and 5 (4: L=Cl; 5: L=C7 H4 NS2 ). One of the key differences between 4 and 5 is the presence of different ancillary ligands at the metal center. The natural bond orbital (NBO) analysis of 1 and 2 shows that there is four lone pairs of electrons on each metal center with a significant amount of d character. Furthermore, the electronic structures and the bonding of these complexes have been established on the ground of quantum-chemical calculations. All of the new compounds were characterized by IR, 1 H, 11 B, 13 C NMR spectroscopy, and X-ray crystallographic analysis." @default.
• W2536350097 created "2016-10-28" @default.
• W2536350097 creator A5036801121 @default.
• W2536350097 creator A5075230954 @default.
• W2536350097 creator A5078754426 @default.
• W2536350097 creator A5078948160 @default.
• W2536350097 date "2016-10-18" @default.
• W2536350097 modified "2023-10-18" @default.
• W2536350097 title "Reactivity of [M₂ (μ-Cl)₂ (cod)₂ ] (M=Ir, Rh) and [Ru(Cl)₂ (cod)(CH₃ CN)₂ ] with Na[H₂ B(bt)₂ ]: Formation of Agostic versus Borate Complexes" @default.
• W2536350097 cites W1542495843 @default.
• W2536350097 cites W1586447830 @default.
• W2536350097 cites W1822419141 @default.
• W2536350097 cites W1967310757 @default.
• W2536350097 cites W1969360633 @default.
• W2536350097 cites W1971599421 @default.
• W2536350097 cites W1972138681 @default.
• W2536350097 cites W1972279940 @default.
• W2536350097 cites W1981116754 @default.
• W2536350097 cites W1983026194 @default.
• W2536350097 cites W1983794742 @default.
• W2536350097 cites W1987097267 @default.
• W2536350097 cites W1988091937 @default.
• W2536350097 cites W1990396044 @default.
• W2536350097 cites W1991061109 @default.
• W2536350097 cites W1997606477 @default.
• W2536350097 cites W2002482043 @default.
• W2536350097 cites W2009236200 @default.
• W2536350097 cites W2009814010 @default.
• W2536350097 cites W2012374007 @default.
• W2536350097 cites W2015723183 @default.
• W2536350097 cites W2018270047 @default.
• W2536350097 cites W2018545745 @default.
• W2536350097 cites W2023271753 @default.
• W2536350097 cites W2024955117 @default.
• W2536350097 cites W2028564369 @default.
• W2536350097 cites W2030687437 @default.
• W2536350097 cites W2033076185 @default.
• W2536350097 cites W2034689891 @default.
• W2536350097 cites W2036814524 @default.
• W2536350097 cites W2038767330 @default.
• W2536350097 cites W2042518706 @default.
• W2536350097 cites W2042944554 @default.
• W2536350097 cites W2045214161 @default.
• W2536350097 cites W2045239086 @default.
• W2536350097 cites W2048438230 @default.
• W2536350097 cites W2054164390 @default.
• W2536350097 cites W2059736393 @default.
• W2536350097 cites W2061816471 @default.
• W2536350097 cites W2063236971 @default.
• W2536350097 cites W2066987645 @default.
• W2536350097 cites W2067674643 @default.
• W2536350097 cites W2085574662 @default.
• W2536350097 cites W2085931678 @default.
• W2536350097 cites W2086957099 @default.
• W2536350097 cites W2089415751 @default.
• W2536350097 cites W2089901760 @default.
• W2536350097 cites W2091331903 @default.
• W2536350097 cites W2107631774 @default.
• W2536350097 cites W2107868383 @default.
• W2536350097 cites W2114289437 @default.
• W2536350097 cites W2115943251 @default.
• W2536350097 cites W2125123611 @default.
• W2536350097 cites W2132525235 @default.
• W2536350097 cites W2136240313 @default.
• W2536350097 cites W2137733479 @default.
• W2536350097 cites W2143981217 @default.
• W2536350097 cites W2144675120 @default.
• W2536350097 cites W2146448700 @default.
• W2536350097 cites W2149190015 @default.
• W2536350097 cites W2156115804 @default.
• W2536350097 cites W2160647578 @default.
• W2536350097 cites W2165502376 @default.
• W2536350097 cites W2171810376 @default.
• W2536350097 cites W2180002404 @default.
• W2536350097 cites W2299355154 @default.
• W2536350097 cites W2312311550 @default.
• W2536350097 cites W2315688789 @default.
• W2536350097 cites W2327121138 @default.
• W2536350097 cites W2332197269 @default.
• W2536350097 cites W2337303497 @default.
• W2536350097 cites W2341306918 @default.
• W2536350097 cites W258052507 @default.
• W2536350097 cites W4205797238 @default.
• W2536350097 cites W4212901513 @default.
• W2536350097 cites W4230151690 @default.
• W2536350097 cites W4232942707 @default.
• W2536350097 cites W4236338127 @default.
• W2536350097 cites W4241762724 @default.
• W2536350097 cites W4252335254 @default.
• W2536350097 doi "https://doi.org/10.1002/chem.201603480" @default.
• W2536350097 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27754568" @default.
• W2536350097 hasPublicationYear "2016" @default.
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