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- W2536950547 abstract "Pure powdered compounds with a general formula Th1-xErx(SiO4)1-x(PO4)x belonging to the zircon-xenotime family were successfully synthesized under hydrothermal conditions (250 °C, 7 days) as recently reported for the preparation of coffinite. Therefore, a thorough, combined PXRD, EDX, EXAFS, Raman, and FTIR analysis showed the formation of a solid solution in agreement with Vegard's law. Moreover, the examination of the local structure shows that the Th-O distances remain close to those found in ThSiO4, whereas the Er-O distances show a significant decrease from 2.38(14) to 2.34(7) Å when increasing the erbium content from x = 0.2 to x = 1. The variation of the local structure also affects the PO43- groups that are surely distorted in the structure." @default.
- W2536950547 created "2016-10-28" @default.
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- W2536950547 date "2016-10-17" @default.
- W2536950547 modified "2023-10-14" @default.
- W2536950547 title "Incorporation of Thorium in the Zircon Structure Type through the Th<sub>1–<i>x</i></sub>Er<sub><i>x</i></sub>(SiO<sub>4</sub>)<sub>1–<i>x</i></sub>(PO<sub>4</sub>)<sub><i>x</i></sub> Thorite–Xenotime Solid Solution" @default.
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- W2536950547 doi "https://doi.org/10.1021/acs.inorgchem.6b01862" @default.
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- W2536950547 hasPublicationYear "2016" @default.
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