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• W2537758097 abstract "A facile, one-pot synthetic method to prepare alkoxo-functionalized homoleptic cyclometalated Ir (III) compounds with facial geometry has been developed. The reaction of Ir(COD)2BF4 with two bipyridine ligands, 2′,6′-dimethoxy-4-methyl-2,3′-bipyridine and 2′,6′,4-trimethoxy-2,3′-bipyridine, afforded the homoleptic Ir (III) compounds Ir[(RO)2(Me)pypy]3 (1) and Ir[(RO)3pypy]3 (2) in good yields. The reaction conditions highly selectively produced the aforementioned Ir (III) compounds with facial geometry. The decomposition temperatures of 1 and 2 were 387 °C and 368 °C, respectively. Both compounds exhibited intense blue phosphorescence (λmax = 452–458 nm) with excellent quantum efficiencies (ΦPL = 0.45–0.52). Phosphorescent organic light-emitting diodes (PHOLEDs) that used these compounds as the dopant material and 9-(3-(9H-carbazol-9-yl)phenyl)-9H-carbazol-3-yl)diphenylphosphine oxide as the host material have been fabricated. The electroluminescent device created using compound 1 at a doping level of 5 wt% exhibited the best performance, with an external quantum efficiency of 15.7–15.5% at a brightness of 10–100 cd/m2 and color coordinates of (0.16, 0.28) at 100 cd/m2." @default.
• W2537758097 created "2016-10-28" @default.
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• W2537758097 date "2017-02-01" @default.
• W2537758097 modified "2023-10-14" @default.
• W2537758097 title "One-pot synthesis of homoleptic iridium (III) dyes created using alkoxo-functionalized bipyridine ligands and these dyes' applications for organic light-emitting diodes" @default.
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• W2537758097 doi "https://doi.org/10.1016/j.dyepig.2016.10.033" @default.
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