FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2538282368> ?p ?o ?g. }

• W2538282368 endingPage "13" @default.
• W2538282368 startingPage "2" @default.
• W2538282368 abstract "Diacetone-d-allose is an important building block for the synthesis of pharmaceutical ingredients. The current batch production process involves a chemical oxidation and a reduction step that include hazardous reagents, produce a large amount of waste and require an extensive downstream processing. Current investigations aim to develop a catalytic reduction process of the intermediate diacetone-d-ketoglucose (DAKG) with molecular hydrogen, a green solvent, and a heterogeneous metal catalyst. Improvement of productivity and simultaneous reduction of the environmental impact shall be achieved by transforming the conventional batch procedure into a continuous process with a stationary catalyst packing. The screening studies presented in this work revealed that high reaction rates and a high selectivity (>98%) can be achieved with a commercial platinum catalyst under mild conditions in an aqueous buffer solution. Transition from batch into a continuous process was realized in several mini-scale fixed bed reactors to provide a fast screening and high mass transfer rates. A high selectivity (99%) and a conversion of 30% was achieved. The results indicate that the reactor performance was influenced by internal diffusion limitations and also by external mass transfer. To attain full conversion of DAKG, the reaction was performed in a random packed bed reactor and a selectivity of >96% was achieved." @default.
• W2538282368 created "2016-10-28" @default.
• W2538282368 creator A5039113762 @default.
• W2538282368 creator A5045509957 @default.
• W2538282368 creator A5060873703 @default.
• W2538282368 creator A5062060112 @default.
• W2538282368 creator A5064693162 @default.
• W2538282368 date "2017-03-01" @default.
• W2538282368 modified "2023-09-27" @default.
• W2538282368 title "Novel continuous catalytic hydrogenation process for the synthesis of diacetone-d-allose" @default.
• W2538282368 cites W1968255980 @default.
• W2538282368 cites W1972135468 @default.
• W2538282368 cites W1980319348 @default.
• W2538282368 cites W1980425523 @default.
• W2538282368 cites W1990809791 @default.
• W2538282368 cites W1992151615 @default.
• W2538282368 cites W1994536524 @default.
• W2538282368 cites W2003609959 @default.
• W2538282368 cites W2013221290 @default.
• W2538282368 cites W2020458487 @default.
• W2538282368 cites W2027068632 @default.
• W2538282368 cites W2035880546 @default.
• W2538282368 cites W2035984142 @default.
• W2538282368 cites W2042886412 @default.
• W2538282368 cites W2043203609 @default.
• W2538282368 cites W2043742427 @default.
• W2538282368 cites W2044904754 @default.
• W2538282368 cites W2045737326 @default.
• W2538282368 cites W2046717945 @default.
• W2538282368 cites W2052202097 @default.
• W2538282368 cites W2052486235 @default.
• W2538282368 cites W2053006127 @default.
• W2538282368 cites W2053621436 @default.
• W2538282368 cites W2056718697 @default.
• W2538282368 cites W2071024380 @default.
• W2538282368 cites W2075283883 @default.
• W2538282368 cites W2090367971 @default.
• W2538282368 cites W2091439639 @default.
• W2538282368 cites W2108071482 @default.
• W2538282368 cites W2113617992 @default.
• W2538282368 cites W2121517213 @default.
• W2538282368 cites W2152783510 @default.
• W2538282368 cites W2317676266 @default.
• W2538282368 cites W2321128093 @default.
• W2538282368 cites W2330969320 @default.
• W2538282368 cites W4240499964 @default.
• W2538282368 doi "https://doi.org/10.1016/j.cep.2016.10.013" @default.
• W2538282368 hasPublicationYear "2017" @default.
• W2538282368 type Work @default.
• W2538282368 sameAs 2538282368 @default.
• W2538282368 citedByCount "5" @default.
• W2538282368 countsByYear W25382823682017 @default.
• W2538282368 countsByYear W25382823682018 @default.
• W2538282368 countsByYear W25382823682019 @default.
• W2538282368 countsByYear W25382823682022 @default.
• W2538282368 crossrefType "journal-article" @default.
• W2538282368 hasAuthorship W2538282368A5039113762 @default.
• W2538282368 hasAuthorship W2538282368A5045509957 @default.
• W2538282368 hasAuthorship W2538282368A5060873703 @default.
• W2538282368 hasAuthorship W2538282368A5062060112 @default.
• W2538282368 hasAuthorship W2538282368A5064693162 @default.
• W2538282368 hasConcept C118792377 @default.
• W2538282368 hasConcept C127413603 @default.
• W2538282368 hasConcept C161790260 @default.
• W2538282368 hasConcept C172658912 @default.
• W2538282368 hasConcept C178790620 @default.
• W2538282368 hasConcept C185592680 @default.
• W2538282368 hasConcept C19577693 @default.
• W2538282368 hasConcept C199360897 @default.
• W2538282368 hasConcept C2780548022 @default.
• W2538282368 hasConcept C40875361 @default.
• W2538282368 hasConcept C41008148 @default.
• W2538282368 hasConcept C42360764 @default.
• W2538282368 hasConcept C43617362 @default.
• W2538282368 hasConcept C51038369 @default.
• W2538282368 hasConcept C518104683 @default.
• W2538282368 hasConceptScore W2538282368C118792377 @default.
• W2538282368 hasConceptScore W2538282368C127413603 @default.
• W2538282368 hasConceptScore W2538282368C161790260 @default.
• W2538282368 hasConceptScore W2538282368C172658912 @default.
• W2538282368 hasConceptScore W2538282368C178790620 @default.
• W2538282368 hasConceptScore W2538282368C185592680 @default.
• W2538282368 hasConceptScore W2538282368C19577693 @default.
• W2538282368 hasConceptScore W2538282368C199360897 @default.
• W2538282368 hasConceptScore W2538282368C2780548022 @default.
• W2538282368 hasConceptScore W2538282368C40875361 @default.
• W2538282368 hasConceptScore W2538282368C41008148 @default.
• W2538282368 hasConceptScore W2538282368C42360764 @default.
• W2538282368 hasConceptScore W2538282368C43617362 @default.
• W2538282368 hasConceptScore W2538282368C51038369 @default.
• W2538282368 hasConceptScore W2538282368C518104683 @default.
• W2538282368 hasLocation W25382823681 @default.
• W2538282368 hasOpenAccess W2538282368 @default.
• W2538282368 hasPrimaryLocation W25382823681 @default.
• W2538282368 hasRelatedWork W1486781939 @default.
• W2538282368 hasRelatedWork W1978882761 @default.
• W2538282368 hasRelatedWork W2018359203 @default.
• W2538282368 hasRelatedWork W2021939235 @default.

• next