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• W2538878544 startingPage "17681" @default.
• W2538878544 abstract "Although a lot of titanium oxo-clusters (TOCs) have been synthesized and characterized, research studies on their application properties are still limited. The work described here is not only aimed at the synthesis and crystal structures of the TOCs, but also aimed at exploration of their potential applications in molecule based fluorescence labelling and photocatalysis. Three heterometallic TOC compounds with lanthanide (Ln) elements Sm(iii) (1), Eu(iii) (2) and Gd(iii) (3) are prepared and their cluster structures are characterized as LnTi11 cages. Compound 2 exhibits the characteristic fluorescence of Eu(iii) and the emission intensity can be decreased upon irradiation and recovered by air oxidation, which is attributed to the energy transfer between Eu(iii) and photo-induced Ti(iii) of the oxo-TiO cluster. The fluorescence intensity of 2 can be significantly increased when treated with 1,10-phenanthroline. The catalytic properties of 2 were determined by the degradation of dyes on a paper substrate. Compound 2 has potential applications as a molecule based fluorescent labelling agent and photodegeneration catalyst." @default.
• W2538878544 created "2016-10-28" @default.
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• W2538878544 date "2016-01-01" @default.
• W2538878544 modified "2023-09-25" @default.
• W2538878544 title "A lanthanide–titanium (LnTi₁₁) oxo-cluster, a potential molecule based fluorescent labelling agent and photocatalyst" @default.
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• W2538878544 doi "https://doi.org/10.1039/c6dt03034c" @default.
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• W2538878544 hasPublicationYear "2016" @default.
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