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- W2539172360 endingPage "118" @default.
- W2539172360 startingPage "106" @default.
- W2539172360 abstract "Stabilization of oxygen vacancies on metal oxides (e.g. TiO2) in liquid phase is an important challenge for the utilization of these materials in artificial photosynthesis, environmental remediation and biomass conversion. To create materials with low-energy barriers for vacancies formation and high stability in aqueous environments, we have developed partially hydrophobic (contact angle ≥90°) TiO2 rutile decorated with Ru nanoparticles. Negligible catalytic activity was observed when hydrophilic (contact angle 51°) 5 wt.% Ru/TiO2 anatase was utilized in hot liquid water, while amphiphilic 5 wt.% Ru/TiO2 rutile (contact angle ∼90°) retained its catalytic activity. Fine-control of crystalline structure (lattice matching) of TiO2 and Ru allowed us to accelerate the rate of reaction, while the high surface hydrophobicity of the support enabled the stabilization of Ti3+ cations in aqueous and organic environments." @default.
- W2539172360 created "2016-10-28" @default.
- W2539172360 creator A5030317742 @default.
- W2539172360 creator A5047708248 @default.
- W2539172360 creator A5065899480 @default.
- W2539172360 creator A5083119913 @default.
- W2539172360 date "2017-02-01" @default.
- W2539172360 modified "2023-10-01" @default.
- W2539172360 title "Enhanced activity and stability of Ru-TiO2 rutile for liquid phase ketonization" @default.
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- W2539172360 doi "https://doi.org/10.1016/j.apcata.2016.10.025" @default.
- W2539172360 hasPublicationYear "2017" @default.
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