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• W2540162681 startingPage "11751" @default.
• W2540162681 abstract "Readily available ethyl chlorofluoroacetate, when treated with a strong base, forms an α-chloro-α-fluorocarbanion that adds to nitroarenes at a position ortho or para to the nitro group with formation of anionic σH adducts. Subsequent base-induced β-elimination of HCl proceeds selectively to give nitrobenzylic α-fluorocarbanions and, upon protonation, ethyl α-fluoro-α-nitroarylacetates." @default.
• W2540162681 created "2016-11-04" @default.
• W2540162681 creator A5042872239 @default.
• W2540162681 creator A5044654291 @default.
• W2540162681 creator A5090210886 @default.
• W2540162681 date "2016-11-07" @default.
• W2540162681 modified "2023-10-18" @default.
• W2540162681 title "Synthesis of α-Fluoro-α-nitroarylacetates via Vicarious Nucleophilic Substitution of Hydrogen" @default.
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• W2540162681 doi "https://doi.org/10.1021/acs.joc.6b02219" @default.
• W2540162681 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27783510" @default.
• W2540162681 hasPublicationYear "2016" @default.
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