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• W2541322759 abstract "A potassium base-promoted formal [2+2] cycloaddition of 2-acyl-2'-vinyl-1,1'-biaryls was developed to afford benzo-fused polycyclic cyclobutanols in a highly stereoselective manner. We demonstrated synthesis of substituted polycyclic aromatic hydrocarbons and these heterocyclic derivatives via this cyclization, followed by an acid-promoted rearrangement. Furthermore, asymmetric total synthesis of phenanthroindolizidine alkaloid (-)-tylophorine was achieved using our methodology and late-stage asymmetric hydrogenation of a cyclic imine." @default.
• W2541322759 created "2016-11-04" @default.
• W2541322759 creator A5009336023 @default.
• W2541322759 date "2016-11-01" @default.
• W2541322759 modified "2023-09-27" @default.
• W2541322759 title "Efficient Synthesis of Polyaromatic Hydrocarbon <i>via</i> a Formal [2+2] Cycloaddition" @default.
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• W2541322759 doi "https://doi.org/10.1248/yakushi.16-00202" @default.
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