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- W2542602015 endingPage "5807" @default.
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- W2542602015 abstract "An oxy-palladation, formal Wagner–Meerwein rearrangement and fluorination cascade has been established for generating fluorinated oxazolidine-2,4-diones and oxazolidin-2-ones. The reaction has a broad substrate scope in which both aryl and alkyl groups can be utilized as efficient migrating groups. Experimental evidence suggests that the reaction is initiated by anti-oxy-palladation of the olefin, followed by oxidative generation of an alkyl PdIV intermediate and a concerted migration–fluorination." @default.
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- W2542602015 date "2016-10-31" @default.
- W2542602015 modified "2023-10-15" @default.
- W2542602015 title "High-Valent Palladium-Promoted Formal Wagner–Meerwein Rearrangement" @default.
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- W2542602015 doi "https://doi.org/10.1021/acs.orglett.6b02706" @default.
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