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- W2542697205 abstract "The first synthesis of anion capped cerium corrole complexes is reported. Unusual clustering of the lanthanide corrole units has been found and the degree of aggregation can be controlled by the choice of the capping ligand. A polymeric structure 1a, with the general formula [Cor-Ce(THF)-Cp-Na]n (Cor = 5,15-bis(2,4,6-trimethylphenyl)-10-(4 methoxyphenyl)-corrole, THF = tetrahydrofuran), is formed using sodium cyclopentadienide (NaCp) and a dimeric structure 2a, with the general formula [Cor-Ce-Tp]2, is formed when potassium tris(pyrazolyl)borate (KTp) is used. Encapsulation of the counter-cation leads to the isolation of the monomeric structures 1b and 2b, with the general formulas [AM(2.2.2-cryptand)][Cor-Cp-X] (AM = Na or K, X = Cp or Tp). The structural and spectroscopic properties of the complexes have been investigated." @default.
- W2542697205 created "2016-11-04" @default.
- W2542697205 creator A5002175536 @default.
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- W2542697205 creator A5018749169 @default.
- W2542697205 creator A5037440170 @default.
- W2542697205 creator A5056647842 @default.
- W2542697205 date "2016-01-01" @default.
- W2542697205 modified "2023-09-27" @default.
- W2542697205 title "Control of clustering behavior in anionic cerium(<scp>iii</scp>) corrole complexes: from oligomers to monomers" @default.
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- W2542697205 doi "https://doi.org/10.1039/c6dt03884k" @default.
- W2542697205 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5127600" @default.
- W2542697205 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27827498" @default.
- W2542697205 hasPublicationYear "2016" @default.
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