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- W2542844034 abstract "Electrochemical oxidation of toluene derivatives in the presence of N-tosyldiphenylsulfilimine gave the corresponding benzylaminosulfonium ions, which were treated with tetrabutylammonium iodide under non-electrolytic conditions to give N-tosylbenzylamines. The transformation serves as a metal- and chemical-oxidant-free method for benzylic C-H amination. Because of high oxidation potential of N-tosyldiphenylsulfilimine the present method can be applied to synthesis of various benzylamines from functionalized toluene derivatives." @default.
- W2542844034 created "2016-11-04" @default.
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- W2542844034 date "2016-11-23" @default.
- W2542844034 modified "2023-10-02" @default.
- W2542844034 title "Metal-Free Benzylic C−H Amination via Electrochemically Generated Benzylaminosulfonium Ions" @default.
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- W2542844034 doi "https://doi.org/10.1002/chem.201604484" @default.
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