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- W2543437822 abstract "An unprecedented reactivity of 3-aminoquinoline-2,4-diones is reported. Under basic conditions, these compounds undergo molecular rearrangement to furnish 1,4-benzodiazepine-2,5-diones. The transformations take place under mild reaction conditions by using 1,1,3,3-tetramethylguanidine, NaOEt, or benzyltrimethylammonium hydroxide as a base. A proposed mechanism of the rearrangement and the conformational equilibrium of 1,4-benzodiazepine-2,5-dione rings are discussed." @default.
- W2543437822 created "2016-11-04" @default.
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- W2543437822 date "2016-11-09" @default.
- W2543437822 modified "2023-09-24" @default.
- W2543437822 title "Synthesis of 1,4-Benzodiazepine-2,5-diones by Base Promoted Ring Expansion of 3-Aminoquinoline-2,4-diones" @default.
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- W2543437822 doi "https://doi.org/10.1021/acs.joc.6b01497" @default.
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