FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2544004001> ?p ?o ?g. }

• W2544004001 endingPage "9138" @default.
• W2544004001 startingPage "9130" @default.
• W2544004001 abstract "Four new alkaline-earth metal-based metal–organic frameworks, [Mg4(TCMTB)2(OAc)2(DMA)2(H2O)3]n (Mg-TCMTB), {[Ca4(TCMTB)2(OH)(DMF)2(H2O)5]·Cl}n (Ca-TCMTB), [Sr4(TCMTB)2(OH)(OAc)(DMA)6(H2O)]n (Sr-TCMTB) and [Ba9(TCMTB)4(NO3)6(DMA)14]n (Ba-TCMTB) (H3TCMTB = 2,4,6-tris[(4′-carboxyphenoxy)methyl]-1,3,5-trimethylbenzene), have been synthesized and structurally characterized. Structural analysis of the MOFs reveals the presence of diverse structures and topologies in these systems due to the conformational flexibility and multiple coordination sites in H3TCMTB. Coordination polymers Mg-TCMTB, Ca-TCMTB and Ba-TCMTB MOFs are three-dimensional frameworks exhibiting 2-fold interpenetration and one-dimensional hexagonal channels, while Sr-TCMTB is a 2-fold interpenetrated layered MOF. The 2D layers in Sr-TCMTB are interconnected through H–O⋯H hydrogen bonds. Increasing ionic radii and coordination number on moving down the group results in the formation of bi-, tetra- and nona-nuclear M–O–M connected inorganic building units. Owing to its smaller size and lower coordination number, framework Mg-TCMTB gives rise to a moderate surface area of 33.0 m2 g−1 (SABET) and 93.8 m2 g−1 (SALang) which is the highest observed among all the four MOFs. Emission studies of the new MOFs reveal the presence of strong photoluminescence at 380 nm." @default.
• W2544004001 created "2016-11-04" @default.
• W2544004001 creator A5025230362 @default.
• W2544004001 creator A5032836538 @default.
• W2544004001 creator A5050276150 @default.
• W2544004001 creator A5067223596 @default.
• W2544004001 date "2016-01-01" @default.
• W2544004001 modified "2023-10-01" @default.
• W2544004001 title "Dependence of the SBU length on the size of metal ions in alkaline earth MOFs derived from a flexible C₃-symmetric tricarboxylic acid" @default.
• W2544004001 cites W1482495550 @default.
• W2544004001 cites W1932286336 @default.
• W2544004001 cites W1964685299 @default.
• W2544004001 cites W1975126160 @default.
• W2544004001 cites W1977577794 @default.
• W2544004001 cites W1978286119 @default.
• W2544004001 cites W1979902340 @default.
• W2544004001 cites W1982745743 @default.
• W2544004001 cites W1996095906 @default.
• W2544004001 cites W1997813480 @default.
• W2544004001 cites W1999937609 @default.
• W2544004001 cites W2007998078 @default.
• W2544004001 cites W2008191636 @default.
• W2544004001 cites W2009518892 @default.
• W2544004001 cites W2012133724 @default.
• W2544004001 cites W2016104362 @default.
• W2544004001 cites W2019290880 @default.
• W2544004001 cites W2019578276 @default.
• W2544004001 cites W2021916843 @default.
• W2544004001 cites W2027808067 @default.
• W2544004001 cites W2029661042 @default.
• W2544004001 cites W2032968295 @default.
• W2544004001 cites W2040215732 @default.
• W2544004001 cites W2040674924 @default.
• W2544004001 cites W2042936361 @default.
• W2544004001 cites W2050036711 @default.
• W2544004001 cites W2057529152 @default.
• W2544004001 cites W2060201755 @default.
• W2544004001 cites W2061934588 @default.
• W2544004001 cites W2063903282 @default.
• W2544004001 cites W2064065591 @default.
• W2544004001 cites W2065162582 @default.
• W2544004001 cites W2066116502 @default.
• W2544004001 cites W2070132142 @default.
• W2544004001 cites W2073042872 @default.
• W2544004001 cites W2079506935 @default.
• W2544004001 cites W2080182825 @default.
• W2544004001 cites W2090596716 @default.
• W2544004001 cites W2091187142 @default.
• W2544004001 cites W2091229453 @default.
• W2544004001 cites W2098292174 @default.
• W2544004001 cites W2099486431 @default.
• W2544004001 cites W2116947538 @default.
• W2544004001 cites W2131350133 @default.
• W2544004001 cites W2142574765 @default.
• W2544004001 cites W2145538332 @default.
• W2544004001 cites W2160641185 @default.
• W2544004001 cites W2164391346 @default.
• W2544004001 cites W2171081520 @default.
• W2544004001 cites W2215484275 @default.
• W2544004001 cites W2230295731 @default.
• W2544004001 cites W2253218100 @default.
• W2544004001 cites W2266539586 @default.
• W2544004001 cites W2312517821 @default.
• W2544004001 cites W2315192871 @default.
• W2544004001 cites W2326269884 @default.
• W2544004001 cites W2326606866 @default.
• W2544004001 cites W2332968412 @default.
• W2544004001 cites W2337038657 @default.
• W2544004001 cites W2415164449 @default.
• W2544004001 cites W2419503305 @default.
• W2544004001 cites W2424355770 @default.
• W2544004001 cites W2858547974 @default.
• W2544004001 cites W2949934272 @default.
• W2544004001 doi "https://doi.org/10.1039/c6ce01821a" @default.
• W2544004001 hasPublicationYear "2016" @default.
• W2544004001 type Work @default.
• W2544004001 sameAs 2544004001 @default.
• W2544004001 citedByCount "21" @default.
• W2544004001 countsByYear W25440040012017 @default.
• W2544004001 countsByYear W25440040012018 @default.
• W2544004001 countsByYear W25440040012019 @default.
• W2544004001 countsByYear W25440040012020 @default.
• W2544004001 countsByYear W25440040012021 @default.
• W2544004001 countsByYear W25440040012022 @default.
• W2544004001 countsByYear W25440040012023 @default.
• W2544004001 crossrefType "journal-article" @default.
• W2544004001 hasAuthorship W2544004001A5025230362 @default.
• W2544004001 hasAuthorship W2544004001A5032836538 @default.
• W2544004001 hasAuthorship W2544004001A5050276150 @default.
• W2544004001 hasAuthorship W2544004001A5067223596 @default.
• W2544004001 hasConcept C112887158 @default.
• W2544004001 hasConcept C145148216 @default.
• W2544004001 hasConcept C147789679 @default.
• W2544004001 hasConcept C150394285 @default.
• W2544004001 hasConcept C154881586 @default.
• W2544004001 hasConcept C161790260 @default.
• W2544004001 hasConcept C165135838 @default.
• W2544004001 hasConcept C178790620 @default.

• next