FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2544802337> ?p ?o ?g. }

• W2544802337 endingPage "425" @default.
• W2544802337 startingPage "418" @default.
• W2544802337 abstract "Glycerol carbonate is one of the most potentially multifunction glycerol-derived compounds. Glycerol is an important by-product of the oleochemical industry. The oligomerization of glycerol carbonate, assisted by the glycerol, results in the production of polyhydroxylated oligomers rich in linear carbonate groups. The polar moieties of these oligomers (Mw < 1000 Da) were supplied by glycerol and glycerol carbonate rather than ethylene oxide as in most commercial surfactants. The insertion of linear carbonate groups into the glycerol-based skeleton rendered the oligomers amphiphilic, resulting in a decrease in air/water surface tension to 57 mN/m. We improved the physical and chemical properties of the oligomers, by altering the type of acylation reaction and the nature of the acyl donor. The polar head is constituted of homo-oligomers and hetero-oligomers. Homo-oligomers are oligoglycerol and/or oligocarbonate, hetero-oligomers are oligo(glycerol-glycerol carbonate). Coprah oligoesters had the best surfactant properties (CMC < 1 mg/mL, πcmc < 30 mN/m), outperforming molecules of fossil origin, such as ethylene glycol monododecyl ether, glycol ethers and fatty acid esters of sorbitan polyethoxylates. The self-assembling properties of oligocarbonate esters were highlighted by their ability to stabilize inverse and multiple emulsions. The oligo-(glycerol carbonate-glycerol ether) with relatively low molecular weights showed properties of relatively high-molecular weight molecules, and constitute a viable “green” alternative to ethoxylated surfactants." @default.
• W2544802337 created "2016-11-04" @default.
• W2544802337 creator A5007964835 @default.
• W2544802337 creator A5010443569 @default.
• W2544802337 creator A5014481412 @default.
• W2544802337 creator A5036323723 @default.
• W2544802337 date "2017-02-01" @default.
• W2544802337 modified "2023-10-18" @default.
• W2544802337 title "Esters of oligo-(glycerol carbonate-glycerol): New biobased oligomeric surfactants" @default.
• W2544802337 cites W1986446800 @default.
• W2544802337 cites W1995142295 @default.
• W2544802337 cites W2002493013 @default.
• W2544802337 cites W2007639386 @default.
• W2544802337 cites W2012587215 @default.
• W2544802337 cites W2017961823 @default.
• W2544802337 cites W2020220806 @default.
• W2544802337 cites W2022152105 @default.
• W2544802337 cites W2027162162 @default.
• W2544802337 cites W2034777386 @default.
• W2544802337 cites W2043350421 @default.
• W2544802337 cites W2044873535 @default.
• W2544802337 cites W2053907697 @default.
• W2544802337 cites W2054186950 @default.
• W2544802337 cites W2057277328 @default.
• W2544802337 cites W2063831281 @default.
• W2544802337 cites W2063985915 @default.
• W2544802337 cites W2067288998 @default.
• W2544802337 cites W2078446690 @default.
• W2544802337 cites W2083716839 @default.
• W2544802337 cites W2084092234 @default.
• W2544802337 cites W2091616681 @default.
• W2544802337 cites W2093528241 @default.
• W2544802337 cites W2114625593 @default.
• W2544802337 cites W2165862721 @default.
• W2544802337 cites W2312880474 @default.
• W2544802337 cites W2318535434 @default.
• W2544802337 cites W2320215838 @default.
• W2544802337 cites W2320687056 @default.
• W2544802337 cites W4297975924 @default.
• W2544802337 doi "https://doi.org/10.1016/j.jcis.2016.10.072" @default.
• W2544802337 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27810510" @default.
• W2544802337 hasPublicationYear "2017" @default.
• W2544802337 type Work @default.
• W2544802337 sameAs 2544802337 @default.
• W2544802337 citedByCount "13" @default.
• W2544802337 countsByYear W25448023372017 @default.
• W2544802337 countsByYear W25448023372018 @default.
• W2544802337 countsByYear W25448023372019 @default.
• W2544802337 countsByYear W25448023372020 @default.
• W2544802337 countsByYear W25448023372021 @default.
• W2544802337 countsByYear W25448023372022 @default.
• W2544802337 countsByYear W25448023372023 @default.
• W2544802337 crossrefType "journal-article" @default.
• W2544802337 hasAuthorship W2544802337A5007964835 @default.
• W2544802337 hasAuthorship W2544802337A5010443569 @default.
• W2544802337 hasAuthorship W2544802337A5014481412 @default.
• W2544802337 hasAuthorship W2544802337A5036323723 @default.
• W2544802337 hasBestOaLocation W25448023372 @default.
• W2544802337 hasConcept C15920480 @default.
• W2544802337 hasConcept C178790620 @default.
• W2544802337 hasConcept C185592680 @default.
• W2544802337 hasConcept C188027245 @default.
• W2544802337 hasConcept C2777516009 @default.
• W2544802337 hasConcept C2780407432 @default.
• W2544802337 hasConcept C2780642029 @default.
• W2544802337 hasConcept C2780659211 @default.
• W2544802337 hasConcept C2780881558 @default.
• W2544802337 hasConcept C521977710 @default.
• W2544802337 hasConcept C55493867 @default.
• W2544802337 hasConcept C58226133 @default.
• W2544802337 hasConcept C67407626 @default.
• W2544802337 hasConceptScore W2544802337C15920480 @default.
• W2544802337 hasConceptScore W2544802337C178790620 @default.
• W2544802337 hasConceptScore W2544802337C185592680 @default.
• W2544802337 hasConceptScore W2544802337C188027245 @default.
• W2544802337 hasConceptScore W2544802337C2777516009 @default.
• W2544802337 hasConceptScore W2544802337C2780407432 @default.
• W2544802337 hasConceptScore W2544802337C2780642029 @default.
• W2544802337 hasConceptScore W2544802337C2780659211 @default.
• W2544802337 hasConceptScore W2544802337C2780881558 @default.
• W2544802337 hasConceptScore W2544802337C521977710 @default.
• W2544802337 hasConceptScore W2544802337C55493867 @default.
• W2544802337 hasConceptScore W2544802337C58226133 @default.
• W2544802337 hasConceptScore W2544802337C67407626 @default.
• W2544802337 hasLocation W25448023371 @default.
• W2544802337 hasLocation W25448023372 @default.
• W2544802337 hasLocation W25448023373 @default.
• W2544802337 hasLocation W25448023374 @default.
• W2544802337 hasLocation W25448023375 @default.
• W2544802337 hasLocation W25448023376 @default.
• W2544802337 hasLocation W25448023377 @default.
• W2544802337 hasOpenAccess W2544802337 @default.
• W2544802337 hasPrimaryLocation W25448023371 @default.
• W2544802337 hasRelatedWork W1964338714 @default.
• W2544802337 hasRelatedWork W2013715628 @default.
• W2544802337 hasRelatedWork W2035311044 @default.
• W2544802337 hasRelatedWork W2160431667 @default.
• W2544802337 hasRelatedWork W2165862721 @default.

• next