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- W2546564164 abstract "Poly[tetra-μ 2 -acetato-κ 8 O : O ′-bis(μ 2 -benzene-1,2-diamine-κ 2 N : N ′)dicadmium], [Cd 2 (CH 3 COO) 4 (C 6 H 8 N 2 ) 2 ] n , (I), and poly[[(μ 2 -acetato-κ 2 O : O ′)(acetato-κ 2 O , O ′)(μ 2 -benzene-1,3-diamine-κ 2 N : N ′)cadmium] hemihydrate], {[Cd(CH 3 COO) 2 (C 6 H 8 N 2 )]·0.5H 2 O} n , (II), have two-dimensional polymeric structures in which monomeric units are joined by bridging acetate and benzenediamine ligands. Each of the Cd II ions has an O 4 N 2 coordination environment. The coordination geometries of the symmetry-independent Cd II ions are distorted octahedral and distorted trigonal antiprismatic in (I) and distorted antiprismatic in (II). Both compounds exhibit an intralayer hydrogen-bonding network. In addition, the water of hydration in (II) is involved in interlayer hydrogen bonding." @default.
- W2546564164 created "2016-11-11" @default.
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- W2546564164 date "2016-11-04" @default.
- W2546564164 modified "2023-09-26" @default.
- W2546564164 title "Two cadmium coordination polymers with bridging acetate and phenylenediamine ligands that exhibit two-dimensional layered structures" @default.
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- W2546564164 doi "https://doi.org/10.1107/s2056989016017382" @default.
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