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- W2546943903 abstract "When two π-conjugated fragments are connected by a bond between two sp2 carbon atoms, a torsion around this bond is expected to break the overall π-conjugation. We show that for specially selected monomers, the π-conjugation is insensitive to torsions around a C-C bond up to about 60°. We provide a number of examples for this very unexpected phenomenon and a simple explanation. We propose that this feature can be incorporated into conjugated polymers to generate semiconducting materials that are extremely insensitive to structural disorder." @default.
- W2546943903 created "2016-11-11" @default.
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- W2546943903 date "2016-11-07" @default.
- W2546943903 modified "2023-10-16" @default.
- W2546943903 title "Very Large π-Conjugation Despite Strong Nonplanarity: A Path for Designing New Semiconducting Polymers" @default.
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- W2546943903 doi "https://doi.org/10.1021/acs.jpclett.6b02367" @default.
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