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- W2547210996 abstract "Four new chiral PNP′ pincer ligands with a scaffold consisting of a planar chiral ferrocene and a centro chiral aliphatic unit were synthesized and characterized. Treatment of anhydrous FeBr2(THF)2 with 1 equiv of the unsymmetrical chiral PNP′ pincer ligands afforded complexes of the general formula [Fe(PNP′)Br2]. In the solid state these complexes adopt a tetrahedral geometry with the PNP′ ligands coordinated in a κ2P,N-fashion, as shown by X-ray crystallography. These complexes react with CO in the presence of NaBH4 to yield hydride complexes of the type [Fe(PNP′)(H)(Br)(CO)], which were isolated and tested as catalysts in the asymmetric hydrogenation of ketones. Enantioselectivities of up to 81% ee were obtained." @default.
- W2547210996 created "2016-11-11" @default.
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- W2547210996 date "2016-11-04" @default.
- W2547210996 modified "2023-10-18" @default.
- W2547210996 title "Iron(II) Complexes Containing Chiral Unsymmetrical PNP′ Pincer Ligands: Synthesis and Application in Asymmetric Hydrogenations" @default.
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- W2547210996 doi "https://doi.org/10.1021/acs.organomet.6b00711" @default.
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