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- W2547579591 abstract "Abstract An all‐solid‐state polymeric membrane Ca 2+ ‐selective electrode based on hydrophobic octadecylamine‐functionalized graphene oxide has been developed. The hydrophobic composite in the ion‐selective membrane not only acts as a transduction element to improve the potential stability for the all‐solid‐state Ca 2+ ‐selective electrode, but also is used to immobilize Ca 2+ ionophore with lipophilic side chains through hydrophobic interactions. The developed all‐solid‐state Ca 2+ ‐selective electrode shows a stable potential response in the linear range of 3.0×10 −7 –1.0×10 −3 M with a slope of 24.7±0.3 mV/dec, and the detection limit is (1.6±0.2 )×10 −7 M ( n =3). Additionally, due to the hydrophobicity and electrical conductivity of the composite, the proposed all‐solid‐state ion‐selective electrode exhibits an improved stability with the absence of water layer between the ion‐selective membrane and the underlying glassy carbon electrode. This work provides a simple, efficient and low‐cost methodology for developing stable and robust all‐solid‐state ion‐selective electrode with ionophore immobilization." @default.
- W2547579591 created "2016-11-11" @default.
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- W2547579591 date "2016-11-02" @default.
- W2547579591 modified "2023-10-14" @default.
- W2547579591 title "An All-solid-state Polymeric Membrane Ca<sup>2+</sup>-selective Electrode Based on Hydrophobic Alkyl-chain-functionalized Graphene Oxide" @default.
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- W2547579591 doi "https://doi.org/10.1002/elan.201600383" @default.
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