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- W254802049 abstract "Three resin-based μ-oxo diiron(III) interface catalysts have been successfully prepared to model the functional properties of methane monooxygenase (MMO). The catalysts were characterized and exhibited the catalytic activities in the oxidation of alkanes to responding alcohols and ketones in acetonitrile at room temperature by 30% hydroperoxide (H 2 O 2 ) or tert-butyl hydroperoxide (TBHP) as the oxidants. For 2,6-di-tert-butylphenol as the substrate, the C-C coupling was found in the two reaction systems. The reaction mechanisms were proposed with the predominant radical mechanism." @default.
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- W254802049 date "2009-01-01" @default.
- W254802049 modified "2023-09-27" @default.
- W254802049 title "Synthesis, Characterization and Catalytic Activity of Resin-based Diiron(III) Interphase Catalysts : Model for Methane Monooxygenase" @default.
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