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- W2548285774 abstract "Determining the local structure of catalyst materials is critical for understanding the mechanism of enhanced electrochemical activity in semiconductor electrode. Here, using X-ray absorption fine structure (XAFS) spectra, we reveal that the local disorder structure is formed for the mixed-phase Co3O4 nanowire arrays due to the interaction between the phases of Co3O4 and Co2(OH)2CO3. Comparing to pure Co3O4 nanowire arrays, the mixed phase sample is richer in Co2+ and the electronic structure is changed by the local structure, which are demonstrated by the X-ray absorption near-edge structure (XANES) spectra. It is deduced that the mixed-phase Co3O4 nanowire arrays with abundant Co2+ sites provide more redox centres in electrochemical reaction than the pure Co3O4 nanowire arrays." @default.
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- W2548285774 date "2016-05-01" @default.
- W2548285774 modified "2023-10-16" @default.
- W2548285774 title "XAFS study on the impact of local structure on electrochemical performance for Co3O4nanowire arrays" @default.
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- W2548285774 doi "https://doi.org/10.1088/1742-6596/712/1/012115" @default.
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