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- W2548360044 endingPage "129" @default.
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- W2548360044 abstract "A simple and reliable methodology is described for preparing the first heterogeneous NNN-pincer-copper hybrid catalyst with a high control over surface composition. The strategy relies on the covalently bonding of 2-aminopyridine to cyanuric chloride-functionalized magnetic nanoparticles followed by complexation with CuI. These claims are confirmed by different characterization methods such as SEM, TEM, FT-IR, TGA, ICP, XRD, and elemental analysis. The finely engineered supported catalyst is employed in the aerobic oxidative coupling of terminal alkynes and click reaction using only 0.38 and 0.04 mol% catalyst, respectively. All reactions perform under solvent-free condition or green solvent H2O. Also, the catalyst is readily recovered and reused for up to 8 and 6 subsequent runs in click and homocoupling reactions without significant loss of activity or leaching." @default.
- W2548360044 created "2016-11-11" @default.
- W2548360044 creator A5075466167 @default.
- W2548360044 creator A5091743082 @default.
- W2548360044 date "2017-01-01" @default.
- W2548360044 modified "2023-09-25" @default.
- W2548360044 title "NNN-pincer-copper complex immobilized on magnetic nanoparticles as a powerful hybrid catalyst for aerobic oxidative coupling and cycloaddition reactions in water" @default.
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- W2548360044 doi "https://doi.org/10.1016/j.molcata.2016.11.007" @default.
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