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• W2548563668 abstract "Evidence for the formation of molecular complexes with strong hydrogen bond with fluorine in lithium fluoride crystals containing impurities of OH̄ ions and magnesium under the action of irradiation are presented. The proofs are based on Fermi resonance perturbation of IR stretching vibration bands in the region of 1800–2300 cm−1. It is established for the first time that the profile of the stretching vibration bands has three types of perturbations owing to Fermi resonance of stretching vibrations with its overtones: (1) the effect on the band profile without perturbation; (2) “Evans hole” at 2080 cm−1; (3) A, B, C bands. Manifestation of these particularities depends on a dose and conditions of a crystal irradiation. It is shown that the IR spectra recorded at a helium temperature confirm that the centers with bands at 1800–2300 cm−1 belong to the complexes with hydrogen bond. It is proposed that the OH̄ ion, HF molecule and fluorine ion to be considered as the main structural units of the complex." @default.
• W2548563668 created "2016-11-11" @default.
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• W2548563668 date "2016-12-01" @default.
• W2548563668 modified "2023-10-12" @default.
• W2548563668 title "Fermi resonance of molecular complexes with strong hydrogen bond in irradiated LiF:OH crystals" @default.
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• W2548563668 doi "https://doi.org/10.1016/j.jfluchem.2016.11.003" @default.
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