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• W2548670627 abstract "This paper reports the successful synthesis of the low symmetry phthalocyanines: metal-free 2,3-bis[2′-(2′′-hydroxyethoxy)ethoxy]-9,10,16,17,23,24-hexa-[Formula: see text]-butoxyphthalocyanine 1H[Formula: see text] and its zinc complex 1Zn along with their nonlinear optical (NLO) behavior in solution and in thin films. 1 H NMR investigations evidenced of higher dissymmetry of electronic density in 1H[Formula: see text] in comparison with 1Zn. This dissymmetry is responsible for unusually higher values of Im[[Formula: see text]]/[Formula: see text], [Formula: see text], and [Formula: see text] for 1H[Formula: see text]in contrast to 1Zn, where the notable effect of heavy-metal enhancement of ISC was expected. Both compounds showed Im[[Formula: see text]]/[Formula: see text] values of the order of 10[Formula: see text] in chloroform which are higher in comparison to the symmetrical octabutoxyphthalocyanine H 2 [(BuO) 8 Pc]. NLO properties of 1H[Formula: see text] were improved via its incorporation into polycarbonate polymeric matrix together with CdSe@CdS-TOPO quantum dots. In such composite the value of Im[[Formula: see text]]/[Formula: see text] was almost three times higher in comparison with 1H[Formula: see text] solution in chloroform. The obtained composites are expected to be perspective components of optical materials, capable of protection against strong light irradiation." @default.
• W2548670627 created "2016-11-11" @default.
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• W2548670627 date "2016-08-01" @default.
• W2548670627 modified "2023-10-17" @default.
• W2548670627 title "Improvement of nonlinear optical properties of phthalocyanine bearing diethyleneglycole chains: Influence of symmetry lowering vs. heavy atom effect" @default.
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• W2548670627 doi "https://doi.org/10.1142/s1088424616501042" @default.
• W2548670627 hasPublicationYear "2016" @default.
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